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Monthly aggregated time series of measured concentrations of Al, Cu, Fe, Mn, Zn, C, N, S, P, K, Na, Mg, Ca in litterfall in the ECSF area in the microcatchment Q2. Litterfall was sampled weekly on the 3 transects of Q2 (Q2.1, Q2.2, Q2.3) with 3 polyethylene mesh collectors (0.5 x 0.5 m) per transect. The samples were dried at 40 °C for one week and stored at the ECSF until transport to Germany or Switzerland for chemical analyses. The replicates at upper, middle and lower slope were bulked per transect and collecting interval and the results were subsequently aggregated per month and transect. Samples were ground to <50 µm with a planetary ball mill (Retsch PM200, Haan, Germany) prior to elemental analysis of C, N, and S by thermal combustion (Elementar Analysensysteme, Hanau, Germany) and acid microwave digestion with concentrated HNO3. Element concentrations in the digested samples were measured by AAS, ICP-OES or ICP-MS.

Weekly time series of water fluxes, pH, electrical conductivity and measured concentrations of Al, Cu, Mn, Zn, Cl, PO4-P, Total P, NH4-N, NO3-N, Total N, S, K, Na, Mg, Ca and Total organic C in stem flow in the ECSF area in the microcatchment Q2. The weekly time series extends between March 1998 and December 2016. Stem flow was sampled weekly in Q2.1 with polyurethane collars on 5 representative tree species: Piptocoma discolor (Kunth) Pruski, Heliocarpus americanus L., Sapium glandulosum (L.) Morong, Cyathea caracasana (Klotzsch) Domin, Cecropia angustifolia Trécul. The five stem flow samples were collected, volume-weighted and bulked to one sample per per collecting interval. Samples were immediately filtered (4-7 µm) in the laboratory of the ECSF and stored at -20 °C until transport in frozen state to Germany or to Switzerland for concentration measurements.

Weekly time series of measured concentrations of Al, Mn, Zn, Cl, PO4-P, Total P, NH4-N, NO3-N, Total N, S, K, Na, Mg, Ca and Total organic C in stem flow in the ECSF area in the microcatchment Q2 (transect Q2.1). The weekly time series extends between March 1998 and May 2013. Stem flow was sampled weekly in Q2.1 with polyurethane collars on 5 representative tree species: Piptocoma discolor (Kunth) Pruski, Heliocarpus americanus L., Sapium glandulosum (L.) Morong, Cyathea caracasana (Klotzsch) Domin, Cecropia angustifolia Trécul. The five stem flow samples were collected, volume-weighted and bulked to one sample per per collecting interval. Samples were immediately filtered (4-7 µm) in the laboratory of the ECSF and stored at -20 °C until transport in frozen state to Germany or to Switzerland for concentration measurements.

Weekly time series of water fluxes, electrical conductivity, pH values and measured concentrations of Al, Mn, Zn, Cl, PO4-P, Total P, NH4-N, NO3-N, Total N, K, Na, Mg, Ca and Total organic C in throughfall in Bombuscaro at 1000 m a.s.l. in NUMEX Plot 12 (control). The weekly time series extends between March 2018 and December 2019. Throughfall was sampled weekly with 20 Hellmann-type collectors. Replicates were collected, volume-weighted and bulked to one sample per plot and sampling period. Electrical conductivity and pH values were measured immediately in unfiltered aliquots in the laboratory at the ECSF. Samples were filtered (4-7 µm) in the laboratory of the ECSF and stored at -20 °C until transport in frozen state to Germany for concentration measurements.

Weekly time series of measured concentrations of Al, Mn, Zn, Cl, PO4-P, Total P, NH4-N, NO3-N, Total N, S, K, Na, Mg, Ca and Total organic C in throughfall in the ECSF area in the microcatchment Q2 (transects Q2.1, Q2.2 and Q2.3). The weekly time series extends between March 1998 and May 2013. Throughfall was sampled with 20 Hellmann-type collectors per transect. Replicates were collected, volume-weighted and bulked to one sample per transect and collecting interval. Samples were immediately filtered (4-7 µm) in the laboratory of the ECSF and stored at -20 °C until transport in frozen state to Germany or to Switzerland for concentration measurements.

Monthly mean nutrient and element concentrations in stem flow from Q2. The monthly values were calculated from weekly measurements. Stem flow was collected from 5 trees in Q2. A list of tree species and tree properties can be found in Fleischbein et al. (2005, Hydrological Processes).

Weekly time series of measured concentrations of Al, Mn, Zn, Cl, PO4-P, Total P, NH4-N, NO3-N, Total N, K, Na, Mg, Ca and Total organic C in precipitation in the ECSF area at the FN3 site on T2 near the ECSF meteorological station. The weekly time series extends between May 2000 and May 2013. Precipitation was sampled with 5 Hellmann-type collectors. Replicates were collected, volume-weighted and bulked to one sample per plot. Samples were immediately filtered (4-7 µm) in the laboratory of the ECSF and stored at -20 °C until transport in frozen state to Germany or to Switzerland for concentration measurements.

Weekly time series of measured concentrations of Al, Cu, Mn, Zn, Cl, PO4-P, Total P, NH4-N, NO3-N, Total N, S, K, Na, Mg, Ca and Total organic C in stream water in the ECSF area in the microcatchment Q2. The weekly time series extends between March 1998 and May 2013. Stream water was sampled weekly upstream of the weir in Q2.1. Samples were immediately filtered (4-7 µm) in the laboratory of the ECSF and stored at -20 °C until transport in frozen state to Germany or to Switzerland for concentration measurements.

Weekly time series of water fluxes, pH, electrical conductivity and measured concentrations of Al, Cu, Mn, Zn, Cl, PO4-P, Total P, NH4-N, NO3-N, Total N, S, K, Na, Mg, Ca and Total organic C in stream water in the ECSF area in the microcatchment Q2. The weekly time series extends between March 1998 and December 2016. Stream water was sampled weekly upstream of the weir in Q2.1. Samples were immediately filtered (4-7 µm) in the laboratory of the ECSF and stored at -20 °C until transport in frozen state to Germany or to Switzerland for concentration measurements.

Weekly time series of measured concentrations of Al, Mn, Zn, Cl, PO4-P, Total P, NH4-N, NO3-N, Total N, S, K, Na, Mg, Ca and Total organic C in litter leachate in the ECSF area in the microcatchment Q2 (transects Q2.1, Q2.2 and Q2.3). The weekly time series extends between March 1998 and May 2013. Litter leachate was sampled on the three transects with zero-tension lysimeters below the organic layer. On each transect 3 replicates at upper, middle and lower slope positions were collected, volume-weighted and bulked to one sample per plot and collecting interval. Samples were immediately filtered (4-7 µm) in the laboratory of the ECSF and stored at -20 °C until transport in frozen state to Germany or to Switzerland for concentration measurements.

Weekly time series of water fluxes, electrical conductivity, pH values and measured concentrations of Al, Mn, Zn, Cl, PO4-P, Total P, NH4-N, NO3-N, Total N, K, Na, Mg, Ca and Total organic C in precipitation from the Bombuscaro site at 1000 m a.s.l. located at the climate station. The weekly time series extends between March 2018 and December 2019. Precipitation was sampled with 5 Hellmann-type collectors. Replicates were collected, volume-weighted and bulked to one sample per plot. Electrical conductivity and pH values were measured immediately in unfiltered aliquots in the laboratory at the ECSF. Samples were filtered (4-7 µm) in the laboratory of the ECSF and stored at -20 °C until transport in frozen state to Germany for concentration measurements.

Weekly time series of measured concentrations of Al, Mn, Zn, Cl, PO4-P, Total P, NH4-N, NO3-N, Total N, S, K, Na, Mg, Ca and Total organic C in soil solution (at 30 cm mineral soil depth) in the ECSF area in the microcatchment Q2 (transects Q2.1, Q2.2 and Q2.3). The weekly time series extends between May 2000 and May 2013. Soil solution was sampled on the 3 transects of Q2 with ceramic suction cups having a pore size of 1 µm installed at 30 cm depth in the mineral soil. On each transect 3 replicates were collected and bulked to one sample per plot and collection interval. Samples were immediately stored at -20 °C until transport in frozen state to Germany or to Switzerland for concentration measurements.

The dataset includes physical and chemical properties of the organic layer and mineral soil at NUMEX San Francisco during sampling campaigns from 2007 to 2009. Following properties were measured: bulk density, horizon thickness, sand, silt and clay content, concentrations of Al, Fe, Mn, Zn, C, N, S, P, K, Na, Mg, Ca, cation exchange capacity, exchangeable cations Ca, Na, Mg, K, Al, Fe, delta 13C and delta 15N values. For details on used methods please see Wullaert, H. (2010): Response of nutrient cycles of an old-growth montane forest in Ecuador to experimental low-level nutrient amendments Johannes Gutenberg University Mainz, phd thesis (FOR816dw ID 885): http://www.tropicalmountainforest.org/publications.do?citid=885

Weekly time series of throughfall fluxes, electrical conductivity, pH values and measured concentrations of Al, Mn, Zn, Cl, PO4-P, Total P, NH4-N, NO3-N, Total N, S, K, Na, Mg, Ca and Total organic C in throughfall in the ECSF area in the microcatchment Q2 (transects Q2.1, Q2.2 and Q2.3). The weekly time series extends between March 1998 and December 2016. Throughfall was sampled with 20 Hellmann-type collectors per transect. Replicates were collected, volume-weighted and bulked to one sample per transect and collecting interval. Samples were immediately filtered (4-7 µm) in the laboratory of the ECSF and stored at -20 °C until transport in frozen state to Germany or to Switzerland for concentration measurements. Electrical conductivity and pH values were measured immediately in unfiltered aliquots in the laboratory of the ECSF.

Weekly time series of measured concentrations of Al, Mn, Zn, Cl, PO4-P, Total P, NH4-N, NO3-N, Total N, K, Na, Mg, Ca and Total organic C in precipitation in the ECSF area at the FN2 site (Camino Canal / Zig-Zag). The weekly time series extends between April 1998 and May 2013. Precipitation was sampled with 5 Hellmann-type collectors. Replicates were collected, volume-weighted and bulked to one sample per plot. Samples were immediately filtered (4-7 µm) in the laboratory of the ECSF and stored at -20 °C until transport in frozen state to Germany or to Switzerland for concentration measurements.

Weekly time series of measured concentrations of Al, Mn, Zn, Cl, PO4-P, Total P, NH4-N, NO3-N, Total N, S, K, Na, Mg, Ca and Total organic C in soil solution (at 15 cm mineral soil depth) in the ECSF area in the microcatchment Q2 (transects Q2.1, Q2.2 and Q2.3). The weekly time series extends between May 2000 and May 2013. Soil solution was sampled on the 3 transects of Q2 with ceramic suction cups having a pore size of 1 µm installed at 15 cm depth in the mineral soil. On each transect 3 replicates were collected and bulked to one sample per plot and collection interval. Samples were immediately stored at -20 °C until transport in frozen state to Germany or to Switzerland for concentration measurements.