Laboratory for
Climatology and Remote Sensing

Abstract:

Future increase of atmospheric nitrogen deposition in tropical regions is expected to have negative impacts on forests ecosystems and related biogeochemical processes. In tropical mountain forests topography causes complex streamflow and rainfall patterns, governing the atmospheric transport of pollutants and the intensity and spatial variability of deposition. The main goal of the current study is to link spatio-temporal patterns of upwind nitrogen emissions and nitrate deposition in the San Francisco Valley (eastern Andes of southern Ecuador) at different altitudinal levels. The work is based on Scanning Imaging Absorption SpectroMeter for Atmospheric CHartographY (SCIAMACHY) retrieved-NO2 concentrations, NOx biomass burning emissions from the Global Fire Emissions Database (GFEDv3), and regional vehicle emissions inventory (SA-INV) for urban emissions in South America. The emission data is used as input for lagrangian atmospheric backward trajectory modeling (FLEXTRA) to model the transport to the study area. The results show that NO3?NO3? concentrations in occult precipitation samples are significantly correlated to long-range atmospheric secondary nitrogen transport at the highest meteorological stations (MSs) only, whereas for NO3?NO3? concentrations in rain samples this correlation is more pronounced at the lower MSs. We conclude that ion concentrations in occult precipitation at the uppermost MSs are mainly linked to distant emission sources via the synoptic circulation impinging the more exposed higher sites. Lower correlations close to the valley bottom are due to a lower occult precipitation frequency and point to a contamination of the samples by local pollution sources not captured by the used emission data sources.

Abstract:

Atmospheric sulfur deposition above certain limits can represent a threat to tropical forests, causing nutrient imbalances and mobilizing toxic elements that impact biodiversity and forest productivity. Atmospheric sources of sulfur deposited by precipitation have been roughly identified in only a few lowland tropical forests. Even scarcer are studies of this type in tropical mountain forests, many of them mega- diversity hotspots and especially vulnerable to acidic deposition. In these places, the topographic complexity and related streamflow conditions affect the origin, type, and intensity of deposition. Furthermore, in regions with a variety of natural and anthropogenic sulfur sources, like active volcanoes and biomass burning, no source emission data has been used for determining the contribution of each source to the deposition. The main goal of the current study is to evaluate sulfate (SO?4) deposition by rain and occult precipitation at two to- pographic locations in a tropical mountain forest of southern Ecuador, and to trace back the deposition to possible emission sources applying back-trajectory modeling. To link upwind natural (volcanic) and anthropogenic (urban/industrial and biomass-burning) sulfur emissions and observed sulfate deposition, we employed state-of-the-art inventory and satellite data, including volcanic passive degassing as well. We conclude that biomass-burning sources generally dominate sulfate deposition at the evaluated sites. Minor sulfate transport occurs during the shifting of the predominant winds to the north and west. Occult precipitation sulfate deposition and likely rain sulfate deposition are mainly linked to biomass-burning emissions from the Amazon lowlands. Volcanic and anthropogenic emissions from the north and west contribute to occult precipitation sulfate deposition at the mountain crest Cerro del Consuelo meteorological station and to rain-deposited sulfate at the upriver mountain pass El Tiro meteorological station.